Purchases

Your invoices are always available in the same place as your order.
Go to My Account >> Your orders, where you will see invoices for that order, which you can download in PDF format

Online Subscriptions

Invoices for subscriptions are under My Account >> Your Online Account
Here, you will see a page titles User Profile, and a tab called Subscription History
All your invoices are in the last column, which you can download in PDF format